An additive-free silicon anode in nanotube morphology as a model lithium ion battery material

نویسندگان

چکیده

Ordered arrays of parallel, cylindrical silicon nanotubes are obtained by aluminothermic reduction SiO2 generated atomic layer deposition (ALD) on nanoporous aluminum oxide templates. The to amorphous Si (a-Si) is characterized a combination X-ray diffraction (XRD), solid-state cross-polarization magic-angle spinning nuclear magnetic resonance (29Si CP-MAS NMR), ultraviolet-visible spectroscopy, attenuated total reflectance infrared spectroscopy (ATR-IR), and photoelectron (XPS). These a-Si nanotube electrochemically active in lithium-ion battery environment when prepared Cu current collectors without any additives. absence the traditional additive carbon black, which an inert conductor, increases proportion capacity associated with faradaic reactions (Li incorporation) respect capacitive component. Electrochemical impedance (EIS) charge-discharge tests demonstrate that morphology yields improved tolerance fast cycling.

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ژورنال

عنوان ژورنال: Electrochimica Acta

سال: 2021

ISSN: ['1873-3859', '0013-4686']

DOI: https://doi.org/10.1016/j.electacta.2021.138522